pH in Strong Chlorate (Electrolytic Cooler)

Introduction

Sodium chlorate is an inorganic compound with the chemical formula NaClO3. It is a white crystalline powder that is readily soluble in water. It is hygroscopic. It decomposes above 300 °C to release oxygen and leave sodium chloride. Several hundred million tons are produced annually, mainly for applications in bleaching paper.

Commercial Use

The main commercial use for sodium chlorate is for makingchlorine dioxide(ClO2). The largest application of ClO2, which accounts for about 95% of the use of chlorate, is in bleaching of pulp. All perchlorate compounds are produced industrially by the oxidation of solutions of sodium chlorate by electrolysis. Sodium chlorate may be used to control a variety of plants including morning glory, canada thistle, johnson grass, bamboo, Ragwort, and St John's wort. The herbicide is mainly used on non-crop land for spot treatment and for total vegetation control on areas including roadsides, fenceways, and ditches. Sodium chlorate is also used as a defoliant and desiccant.

Application Overview

Industrially, sodium chlorate is produced by the electrolysis of a hot sodium chloride solution:

NaCl+3H2O→NaClO3 +3H2

In chemistry and manufacturing, electrolysis is a method of using a direct electric current (DC) to drive an otherwise non- spontaneous chemical reaction. Electrolysis is commercially highly important as a stage in the separation of elements from naturally occurring sources such as ores using an electrolytic cell. The voltage that is needed for electrolysis to occur is called the decomposition potential.

This reaction progresses in heat (at least 70 degrees Celsius), and controlled pH. In lower temperature or with high pH another reaction progresses:

2 NaCl + H2O → NaClO + NaCl + H2

The Chloralkali process is an industrial process for the electrolytic production of sodium chlorate. It can also be synthesized by passing chlorine gas through a solution of sodium hydroxide. It is then purified by crystallization.

Typical Process Details: 

Fluid	Strong Chlorate (Composition: NaCl 8%, NaClO3 36%, Na2Cr2O7 0.3%, Water Balance. NaOCl 2 to 5 gpl, pH 5 to 7)
Press Nor/Max	1.1 / 1.8 kg/cm2 (g)
Temp Nor/Max/Min	85 / 90 / 25 deg.C
Design Parameters:	Pressure - FV/6.11 kg/cm2 (g) & Design temperature- 117 deg.C
Density	1330 kg/m3 @ N.O.C
pH Nor/Max/Min	(5.8-6.2) / 6.8 / 4.5
Installation	Insertion type
Insertion Length	Minimum 60 mm

Typical Problems:

Frequent cleaning

Remedies:

Use of differential sensor